Dual door entry to exciplex emission in a chimeric DNA duplex containing non-nucleoside-nucleoside pair

作者:Bag Subhendu Sekhar*; Talukdar Sangita; Kundu Rajen; Saito Isao; Jana Subhashis
来源:Chemical communications, 2014, 50(7): 829-832.
DOI:10.1039/c3cc46967k

摘要

Dual door entry to exciplex formation was established in a chimeric DNA duplex wherein a fluorescent non-nucleosidic base surrogate (S-OxoPy) is paired against a fluorescent nucleosidic base surrogate (B-TPhen(Do)). Packing of the nucleobases via intercalative stacking interactions led to an exciplex emission either via FRET from the donor B-TPhen(Do) or direct excitation of the FRET acceptor S-OxoPy.

  • 出版日期2014