Gold- and silver-catalyzed allylic alkylation of 1,3-dicarbonyl compounds with allylic alcohols

作者：Kothandaraman Prasath; Rao Weidong; Zhang Xiaoxiang; Chan Philip Wai Hong^*

来源：Tetrahedron, 2009, 65(9): 1833-1838.

DOI：10.1016/j.tet.2008.11.102

A highly efficient gold- and silver-catalyzed allylic alkylation of 1,3-dicarbonyl compounds with allylic alcohols has been developed. The reaction was shown to proceed expediently for a wide variety of 1,3-dicarbonyl compounds and allylic alcohols, including 1 degrees and terminal ones, under very mild conditions at room temperature in good to excellent yields (55-96%).

• 出版日期2009-2-28
• 单位南阳理工学院