A Water-Stable 3D Luminescent Metal-Organic Framework Based on Heterometallic [(Eu6ZnII)-Zn-III] Clusters Showing Highly Sensitive, Selective, and Reversible Detection of Ronidazole

作者：Zhang, Qingfu^*; Lei, Mingyuan; Yan, Hui; Wang, Jinyun; Shi, Yang

来源：Inorganic Chemistry, 2017, 56(14): 7610-7614.

DOI：10.1021/acs.inorgchem.7b01156

• NITROAROMATIC EXPLOSIVES
• COORDINATION POLYMERS
• AQUEOUS-MEDIUM
• PICRIC ACID
• PHOTOLUMINESCENCE
• CATIONS
• SENSOR
• SERIES
• FILMS
• IONS

A water-stable 3D luminescent metal organic framework (MOP), [Eu6Zn(mu 3-OH)(8)(NDC)(6)(H2O)(6)] (1), constructed from heterometallic [(Eu6ZnII)-Zn-III] clusters and electron-rich pi-conjugated 1,4-naphthalenedicarboxylic acid (H2NDC) ligands exhibits highly sensitive, selective, and reversible detection of ronidazole, which represents the first example of luminescent MOFs based on Ln-TM heterometallic clusters for the detection of antibiotics in aqueous solution.

• 出版日期2017-7-17
• 单位聊城大学; 中国科学院福建物质结构研究所