Building Block Controlled Cd(II) Coordination Polymers from One Dimension Chain to Three Dimension Network

作者：Wang Xue Wei; Sun Jing Wen; Zhang Hua^*; Hou Guang Feng; Li Guang Ming

来源：Journal of Inorganic and Organometallic Polymers and Materials, 2015, 25(5): 1218-1225.

DOI：10.1007/s10904-015-0230-5

• N-ligands
• Cadmium
• Coordination polymer
• Building block
• Luminescence

Three new N-(5-amino-2-methylphenyl)-4-(3-pyridyl)-2-pyrimidineamine Cd(II) coordination polymers, namely, {[Cd(AMPPA)(2)(H2O)(2)]center dot(NO3)(2)center dot H2O}(n) (1), {[Cd(AMPPA)(2)(ipa)]center dot 2H(2)O}(n) (2) and {[Cd(AMPPA)(2)(Hbtc)]center dot 2H(2)O}(n) (3) (AMPPA = N-(5-amino-2-methylphenyl)-4-(3-pyridyl)-2-pyrimidineamine, H(2)ipa = isophthalic acid and H(3)btc = 1,3,5-benzenetricarboxylic acid) have been synthesized under hydrothermal conditions. X-ray diffraction analysis reveals that complex 1 exhibits one dimension (1D) coordination polymers when only the AMPPA ligand was employed. With the introduction of the building blocks (H(2)ipa and H(3)btc) into the reaction system of 1, complexes 2 with 2D layer and 3 with 3D networks were isolated, respectively. The effect of the building blocks in the construction of complexes 1-3 has been discussed. In addition, all complexes display strong luminescence in the solid state.
Three N-(5-Amino-2-methylphenyl)-4-(3-pyridyl)-2-pyrimidineamine cadmium coordination polymers have been designed and isolated by the introduction of the building blocks of H(2)ipa and H(3)btc featuring 1D chain, 2D layer and 3D network with strong luminescence in the solid state.

• 出版日期2015-9
• 单位黑龙江大学