Selective encapsulation of volatile and reactive methyl iodide

作者:Horng Yih Chern*; Huang Pin Shen; Hsieh Chang Chih; Kuo Chih Hong; Kuo Ting Shen
来源:Chemical Communications, 2012, 48(70): 8844-8846.
DOI:10.1039/c2cc34346k

摘要

A simple organic molecular container can selectively encapsulate the volatile and highly reactive MeI through hydrogen-bonding interactions in solution. The remarkable encapsulation of MeI without self-methylation of the container appears to be determined by the complementary binding sites and the rigidity of the hydrogen-bonding array constrained by the molecular framework.

  • 出版日期2012