Aerosol-assisted synthesis of mesoporous titania nanoparticles with high surface area and controllable phase composition

作者：Wu Zhiwang^*; Lu Yunfeng

来源：Journal of Sol-Gel Science and Technology, 2010, 53(2): 287-292.

DOI：10.1007/s10971-009-2089-9

• Titania
• Mesoporous
• Nanoparticles
• Sol-gel
• Aerosol
• Self-assembly
• Phase transition

Mesoporous titania nanoparticles (denoted as MTN) with high surface area (e.g., 252 m(2) g(-1)) were prepared using tetrapropyl orthotitanate (TPOT) as a titania precursor and 10-20 nm or 20-30 nm silica colloids as templates. Co-assembly of TPOT and silica colloids in an aerosol-assisted process and immediate calcination at 450 A degrees C resulted in anatase/silica composite nanoparticles. Subsequent removal of the silica colloids from the composite by NaOH solution created mesopores in the TiO(2) nanoparticles with pore size corresponding to that of silica colloids. Effects of silica colloids'; contents on MTN porosity and crystallites'; growth at a higher calcination temperature (e.g., 1000 A degrees C) were investigated. Silica colloids suppressed the growth of TiO(2) crystallites during calcination at a higher calcination temperature and controllable contents of the silica colloids in precursor solution resulted in various atomic ratios of anatase to rutile in the calcinated materials. The mesostructure and crystalline structure of these titania materials were characterized by transmission electron microscope (TEM), scanning electron microscope (SEM), X-ray diffraction (XRD), differential thermal analysis (DTA)-thermo-gravimetric analysis (TGA), and N(2) sorption.

• 出版日期2010-2