Stabilization of Nanoparticle Shells by Competing Interactions

作者：Mani Ethayaraja; Sanz Eduardo; Bolhuis Peter G; Kegel Willem K^*

来源：Journal of Physical Chemistry C, 2010, 114(17): 7780-7786.

DOI：10.1021/jp1004067

We demonstrate a mechanism to intrinsically stabilize a hollow shell composed of individual nanoparticles. Using Monte Carlo simulations, we show that if nanoparticles that interact via short-range attraction and long-range repulsion are assembled on a template, the resulting shell can be stabilized upon the removal of the template. The interplay of attractive and repulsive interactions provides energy barriers that dynamically arrest the particles and stabilize the shell. We present a well-defined stability region in the interaction parameters space. We find a transition from single layered to multilayered stable shell by increasing the range of attraction, and show that the mechanism is not limited to spherical shells but can also be extended to stabilize nonspherical shells such as torus shells. This study can potentially be useful in understanding and engineering the assembly of nanoparticles into hollow objects of various shapes.

• 出版日期2010-5-6