A single-chain magnet based on linear [(Mn2MnII)-Mn-III] units

作者：Papatriantafyllopoulou Constantina; Zartilas Sotiris; Manos Manolis J; Pichon Celine; Clerac Rodolphe; Tasiopoulos Anastasios J^*

来源：Chemical Communications, 2014, 50(94): 14873-14876.

DOI：10.1039/c4cc05687f

The synthesis, structural characterization and magnetic properties of a 1D coordination polymer based on a linearmixed valent [(Mn2MnII)-Mn-III] repeating unit are described. It displays single-chain magnet (SCM) behaviour with an energy barrier of similar to 38 K and represents the first example of a mixed valent Mn-carboxylate SCM with a linear architecture.

• 出版日期2014