Mechanism of cathodic reduction of cobalt pyrophosphate complex

作者:Krasikov A V*; Krasikov V L
来源:Russian Journal of Applied Chemistry, 2012, 85(5): 736-741.
DOI:10.1134/S1070427212050096

摘要

Potentiostatic and potentiodynamic methods were employed to study the kinetics of electrochemical reduction of the pyrophosphate cobalt complex to the metal from electrolytes of various compositions in the atmosphere of hydrogen. The reaction orders of cobalt reduction with respect to pyrophosphate anions and hydroxy ions were found. A stage-by-stage mechanism of the cathodic reduction of cobalt was suggested.

  • 出版日期2012-5

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