摘要

Biomineralization-inspired approaches are environmentally friendly processes for developing organic/inorganic hybrids with ordered structures. This study demonstrates a biomineralization-inspired approach that is expanded to form organic/inorganic hybrid thin films based on a zinc-layered compound with an organic molecule. The interactions between the acidic polymers and the zinc ions transiently inhibit crystallization in solution, thereby inducing crystallization on/in the insoluble polymer templates. In addition, poly(vinyl alcohol) provides a template for the specific crystallographic orientation of the zinc-layered compounds. The cooperative effects of the soluble and insoluble macromolecular templates lead to the structural and orientational control of organic/inorganic hybrids based on a zinc-layered compound with an organic molecule.

  • 出版日期2017-10