Nitrogen-Enriched Core-Shell Structured Fe/Fe3C-C Nanorods as Advanced Electrocatalysts for Oxygen Reduction Reaction

作者:Wen, Zhenhai; Ci, Suqin; Zhang, Fei; Feng, Xinliang*; Cui, Shumao; Mao, Shun; Luo, Shenglian; He, Zhen; Chen, Junhong
来源:Advanced Materials, 2012, 24(11): 1399-1404.
DOI:10.1002/adma.201104392

摘要

A cost- effective route for the preparation of Fe3C- based core- shell structured catalysts for oxygen reduction reactions was developed. The novel catalysts generated a much higher power density (i. e., three times higher at Rex of 1 O) than the Pt/ C in microbial fuel cells. Furthermore, the N- Fe/ Fe3C@ C features an ultralow cost and excellent long- term stability suitable for mass production.