Size-Selective Vapochromic Platinum(II) Complex with a Sterically Demanding Pincer-Type N-Heterocyclic Carbene Ligand

作者：Lee Chen Shiang; Zhuang Rui Rui; Sabiah Shahulhameed; Wang Ju Chun; Hwang Wen Shu^*; Lin Ivan J B

来源：Organometallics, 2011, 30(14): 3897-3900.

DOI：10.1021/om200253f

A pyridine-based pincer-type N-heterocyclic carbene complex of Pt(II),[Pt(II)(C-mes boolean AND N boolean AND C)CO] (PF6)(2) (C-mes boolean AND N boolean AND C = 2,6-bis(1-mestylimidazol-2-ylidenyl)pyridine), displays size-selective vapochromic behavior upon exposure to small molecules with donor atoms. An acetone adduct showing a weak interaction between acetone and a C equivalent to O ligand is also structurally determined.

• 出版日期2011-7-25
• 单位东华大学; 苏州大学