Activated Amorphous Carbon With High-Porosity Derived From Camellia Pollen Grains as Anode Materials for Lithium/Sodium Ion Batteries

作者：Xu, Kaiqi; Li, Yunsha; Xiong, Jiawen; Ou, Xing; Su, Wei; Zhong, Guobin; Yang, Chenghao^*

来源：Frontiers in Chemistry, 2018, 6: 366.

DOI：10.3389/fchem.2018.00366

• activated amorphous carbon
• anode
• high porosity
• lithium ion batteries
• sodium ion batteries

Carbonaceous anode materials are commonly utilized in the energy storage systems, while their unsatisfied electrochemical performances hardly meet the increasing requirements for advanced anode materials. Here, activated amorphous carbon (MC) is synthesized by carbonizing renewable camellia pollen grains with naturally hierarchical structure, which not only maintains abundant micro- and mesopores with surprising specific surface area (660 m(2) g(-1)), but also enlarges the interlayer spacing from 0.352 to 0.4 nm, effectively facilitating ions transport, intercalation, and adsorption. Benefiting from such unique characteristic, MC exhibits 691.7 mAh g(-1) after 1200 cycles at 2 A g(-1), and achieves 459.7, 335.4, 288.7, 251.7, and 213.5 mAh g(-1) at 0.1, 0.5, 1, 2, 5 A g(-1) in rate response for lithium-ion batteries (LIBs). Additionally, reversible capacities of 324.8, 321.6, 312.1, 298.9, 282.3, 272.4 mAh g(-1) at various rates of 0.1, 0.2, 0.5, 1, 2, 5 A g(-1) are preserved for sodium-ion batteries (SIBs). The results reveal that the MC anode derived from camellia pollen grains can display excellent cyclic life and superior rate performances, endowing the infinite potential to extend its applications in LIBs and SIBs.

• 出版日期2018-9-4
• 单位华南理工大学