A novel K-ion battery: hexacyanoferrate(II)/graphite cell

作者：Bie, Xiaofei; Kubota, Kei; Hosaka, Tomooki; Chihara, Kuniko; Komaba, Shinichi^*

来源：Journal of Materials Chemistry A, 2017, 5(9): 4325-4330.

DOI：10.1039/c7ta00220c

• PRUSSIAN BLUE
• ELECTRODE MATERIALS
• SUPERIOR CATHODE
• OPEN FRAMEWORK
• SODIUM
• INTERCALATION
• CORROSION
• ALKALI

Recently, research on novel and low cost batteries has been widely conducted to realize large-scale energy storage systems. However, few of the battery systems have delivered performance equal to that of Li-ion batteries. Herein, we propose non-aqueous K-ion batteries by developing hexacyanoferrate(II) compounds (so-called Prussian blue analogues), K1.75Mn[FeII(CN)(6)] (0.93)center dot 0.16H(2)O and K1.64Fe[FeII(CN)(6)](0.89)center dot 0.15H(2)O, as affordable positive electrode materials. In particular, K1.75Mn [FeII(CN)(6)](0.93)center dot 0.16H(2)O prepared by a simple precipitation process delivers a high capacity of 141 mA h g(-1) at 3.8 V as the average operating potential, resulting in a comparable energy density to that of LiCoO2, with excellent cyclability and rate performance in K halfcells. Operando X-ray diffraction measurements reveal that the excellent electrochemical performance of this material is attributed to its open and flexible framework, which can realize fully reversible K+ extraction/insertion and a structural change from monoclinic to tetragonal via cubic phases. For the first time, we demonstrate an inexpensive high-voltage K-ion full cell with a K1.75Mn[Fe(CN)(6)](0.93)center dot 0.16H(2)O/graphite configuration to prove its feasibility as a new promising battery system for an environmentally friendly future.

• 出版日期2017-3-7