A new hydrogen bonding motif involved in self-recognition in the solid state by functionalised macrocycles

作者:Brelot Lydia; Cao Xiao yu; Harrowfield Jack*; Lehn Jean Marie; Rissanen Kari; Russo Luca
来源:CrystEngComm, 2011, 13(7): 2346-2349.
DOI:10.1039/c0ce00814a

摘要

Self-recognition within the crystal lattices of three functionalised macrocycles results in the formation of arrays of remarkably similar hermaphroditic pairs of macrocycles. In the case of two of the macrocycles containing acylhydrazine substituents, a hitherto unknown recognition pattern is found in the interaction of the hydrazine moiety with crown-ether oxygen atoms.

  • 出版日期2011