Umpolung catalyzed by organophosphines: efficient beta,beta-dimerization of vinylphosphonates affording linear dimers

作者:Wang Xiang Bo*; Saga Yuta; Shen Ruwei; Fujino Hiroyoshi; Goto Midori; Han Li Biao
来源:RSC Advances, 2012, 2(14): 5935-5937.
DOI:10.1039/c2ra20704d

摘要

Trimethylphosphine efficiently catalyzed the dimerization reaction of vinylphosphorus compounds to selectively afford the linear non-branched tail-to-tail beta,beta-dimerization dimers via umpolung of the substrates.

  • 出版日期2012