Diaqua-2 kappa(2)O-bis(mu-1-oxido-2-naphthoato)1:2 kappa(3)O(1),O(2):O(2)';2:3 kappa(3)O(2):O(1),O(2)'-bis(1-oxido-2-naphthoato)-1 kappa(1)O(2),O(2);3 kappa(2)O(1),O(2)-hexapyridine-1 kappa(2)N,2 kappa(2)N,3 kappa(2)N-trimanganese(II/III) pyridine disolvate dihydrate

作者：Yang Hua; Chen Yuting; Li Dacheng^*; Wang Daqi

来源：Acta Crystallographica Section E-Structure Reports Online, 2008, 64: M1622-U1318.

DOI：10.1107/S1600536808038439

The title complex, [Mn(3)(C(11)H(6)O(3))(4)(C(5)H(5)N)(6)(H(2)O)(2)]center dot 2H(2)O center dot 2C(5)H(5)N, is a trinuclear mixed oxidation state complex of (1) over bar symmetry. The three Mn atoms are six-coordinated in the shape of distorted octahedra, each coordinated with an O(4)N(2) set of donor atoms, where the ligands exhibit mono- and bidentate modes. However, the coordination of the Mn(II) ion located on the inversion centre involves water molecules at two coordination sites, whereas that of the two symmetry-related Mn(III) ions involves an O(4)N(2) set of donor atoms orginating from the organic ligands. Intramolecular C-H center dot center dot center dot pi interactions between neighbouring pyridine ligands stabilize this arrangement. A two-dimensional network parallel to (001) is formed by intermolecular O-H center dot center dot center dot O hydrogen bonds.

• 出版日期2008-12
• 单位德州学院; 聊城大学