Alcohol responsive 2D coordination network of 3-(4-pyridyl)benzoate and Zinc(II)

作者：Mehlana Gift; Ramon Gaelle; Bourne Susan A^*

来源：Zeitschrift fur Kristallographie-Crystalline Materials, 2013, 228(7): 318-322.

DOI：10.1524/zkri.2013.1607

• Coordination network
• Guest exchange
• Thermal analysis
• Alcohol sorption

The solvothermal reaction of 3-(4-pyridyl)benzoic acid and zinc nitrate yielded a 2D network with an sql topology. Both elemental analysis and single crystal X-ray diffraction studies confirmed the formula of the compound as {[Zn(34pba)(2)] center dot (0.5 DMF) center dot (0.5 H2O)}(n) (1). At room temperature, the desolvated phase of 1, 1d, absorbs methanol, ethanol, 1-propanol and 1-butanol but not water vapour.

• 出版日期2013