A combined experimental and theoretical investigation on solvent-dependent luminescence behavior of a Cu(I)-MOF

作者：Wang, Jun^*; Gu, Chu-Ying; Li, Qing-Lin; Lu, Lu; Liu, Jian-Qiang; Liu, Wei-Cong; Yadav, Reena; Kumar, Abhinav; Ng, Seik Weng

来源：Inorganic Chemistry Communications, 2015, 61: 82-84.

DOI：10.1016/j.inoche.2015.08.025

• Threading network
• Luminescence
• Sensing effect

A new Cu(I)-based complex with chemical formulae [Cu-7(CN)(7)(4,4'-bipy)] (1), (4,4'-bipy = 4,4'-bipyridine) has been synthesized and structurally characterized. Single-crystal X-ray analyses reveal that compound 1 exhibits threading network constructed by a 2D sheet and 1D chain. The photoluminescent property of I indifferent solvents has been investigated and corroborated by theoretical calculations. The obtained results are in good agreement with the results of solvent-dependent luminescence experimental behaviors. An extended analysis of experimental and computational result for 1 indicates that strong metal solvent bonding interaction plays a dominant role in the sensing of various solvents.

• 出版日期2015-11
• 单位广东医科大学; 四川轻化工大学