A self-complexing and self-assembling pillar[5]arene

作者:Strutt Nathan L; Zhang Huacheng; Giesener Marc A; Lei Juying; Stoddart J Fraser*
来源:Chemical communications, 2012, 48(11): 1647-1649.
DOI:10.1039/c2cc16030g

摘要

A monofunctionalised pillar[5]arene derivative carrying a viologen side chain which exhibits self-complexation in dilute dichloromethane solutions forms supramolecular daisy chain polymers and eventually organogels as its concentration is increased three-fold over the range from 0.1 to 100 mM.