Anisotropic Thermal Characteristics of Graphene-embedded Polyimide Composite Sheets

作者：Park Seong Yeob; Bae Jong Seong; Kim Jin Gyu; Oh Min Wook; Kim Jungsoo; Nam Dae Geun; Yeum Jeong Hyun^*; Oh Weontae^*

来源：Polymers and Polymer Composites, 2016, 24(5): 315-321.

DOI：10.1177/096739111602400502

• Graphene
• Thermal conductivity
• Thermal expansion coefficient
• Composite film
• Stress

Polyimide-graphene (PIG) composites were prepared, and their thermal properties were characterized as films or sheets. Graphene loadings were controlled up to 8 wt.% or 12 wt.% in their composites. The graphenes used in this work were prepared by the chemical treatment of graphite. The as-prepared polyimide-graphene composites were thermally characterized in films or sheets. The thermal conductivities of the PIG sheets were separately analyzed in both in-plane and out-of-plane directions. The thermal expansion coefficients (TECs) of the PIG composites slightly changed with the amount of graphene added to the composites. The in-plane thermal conductivities were higher than the out-of-plane thermal conductivities, and the thermal conductivities of both directions proportionally increased with the graphene loadings in the PIG composites. The temperature-dependent stresses of the composite films monotonically decreased with the graphene loadings. The experimentally obtained thermal characteristics of the polyimide-graphene composites were compared and discussed on the basis of the composite morphologies.

• 出版日期2016