Acetyl Chloride-Silver Nitrate-Acetonitrile: A Reagent System for the Synthesis of 2-Nitroglycals and 2-Nitro-1-Acetamido Sugars from Glycals

作者:Kancharla Pavan K; Reddy Y Suman; Dharuman Suresh; Vankar Yashwant D*
来源:Journal of Organic Chemistry, 2011, 76(14): 5832-5837.
DOI:10.1021/jo200475h

摘要

A new reagent system comprising acetyl chloride, silver nitrate, and acetonitrile has been developed for the synthesis of 2-nitroglycals from the corresponding glycals. Under certain conditions, the formation of 2-nitro-1-acetamido sugars has also been observed. In addition, a few other non-carbohydrate-derived olefins also gave the corrresponding conjugated nitroolefins.

  • 出版日期2011-7-15