X-Ray crystal structure of a heterobimetallic Al-Zn-oxide complex

作者:Schulz Stephan*; Spielmann Jan; Blaeser Dieter; Woelper Christoph
来源:Chemical communications, 2011, 47(9): 2676-2678.
DOI:10.1039/c0cc05599a

摘要

OH/R (R = H, Me, i-Bu) exchange was observed in reactions of [MesnacnacZn(mu-OH)](2) (1) with metal complexes L(n)MR, whereas DippnacnacAl(Me) OH reacts with MesnacnacZnH with elimination of H(2) and formation of the heterobimetallic Al-Zn-oxide complex MesnacnacZnOAl(Me)Dippnacnac 2.

  • 出版日期2011