Atom transfer radical polymerization of 2,5-bis[(4-hexyloxyphenyl)oxycarbonyl]styrene

作者：Yi Y^*; Fan XH; Zhao YF; Chen XF; Wan XH; Zhou QF

来源：Chinese Journal of Polymer Science, 2005, 23(3): 249-253.

DOI：10.1142/S0256767905000357

• atom transfer radical polymerization
• liquid crystalline polymer

A side-on liquid crystalline monomer, 2,5-bis [(4-hexyloxyphenyl)oxycarbonyl] styrene) (HPCS), was successfully polymerized via atom transfer radical polymerization (ATRP). The polymerization was catalyzed by CuBr/PMDETA in chlorobenzene at 90° C with (1-bromoethyl)benzene as the initiator. The polymers have narrow MWD. It is the second example of mesogen-jacketed liquid crystalline polymer (MJLCP) prepared by ATRP.

• 出版日期2005-5
• 单位北京大学