A non-interpenetrating 2D coordination polymer from a (CH2)(8) spacer-based highly flexible linear ligand and AgCF3CO2

作者:Chen, CL; Su, CY*; Cai, YP; Zhang, HX; Xu, AW; Kang, BS
来源:New Journal of Chemistry, 2003, 27(5): 790-792.
DOI:10.1039/b301777j

摘要

Reaction of a (CH2)(8) spacer-based ligand, 1,8-bis(8-thioquinolyl)octane ( C8TQ), with AgCF3CO2 affords a designed non-interpenetrating 2D brick-wall coordination polymer [Ag-2(C8TQ) (CF3CO2)(2)](n), composed of thio-bridged helical chains racemically aligned and further connected by the (CH2)(8) spacers, while weak F...F interactions between ligated CF3CO2- fabricate the 3D supramolecular architecture.