摘要
Reaction of a (CH2)(8) spacer-based ligand, 1,8-bis(8-thioquinolyl)octane ( C8TQ), with AgCF3CO2 affords a designed non-interpenetrating 2D brick-wall coordination polymer [Ag-2(C8TQ) (CF3CO2)(2)](n), composed of thio-bridged helical chains racemically aligned and further connected by the (CH2)(8) spacers, while weak F...F interactions between ligated CF3CO2- fabricate the 3D supramolecular architecture.
- 出版日期2003
- 单位中国科学院; 中山大学