Stabilized Naked Sub-nanometric Cu Clusters within a Polymeric Film Catalyze C-N, C-C, C-O, C-S, and C-P Bond-Forming Reactions

作者：Oliver Messeguer Judit; Liu Lichen; Garcia Garcia Saray; Canos Gimenez Claudia; Dominguez Irene; Gavara Rafael; Domenech Carbo Antonio; Concepcion Patricia; Leyva Perez Antonio^*; Corma Avelino

来源：Journal of the American Chemical Society, 2015, 137(11): 3894-3900.

DOI：10.1021/jacs.5b00222

Sub-nanometric Cu clusters formed by endogenous reduction of Cu salts and Cu nanopartides are active and selective Catalysts for C-N, C-C, C-O, C-S, and C-P bond-forming reactions. Sub-nanometric Cu clusters have also been generated within a polymeric film and stored with full stability for Months. In this way, they are ready to be used on demand and maintain high activity (TONs tip to 10(4)) and selectivity for the above reactions. A potential mechanism for the formation of the sub-nanometric dusters and their electronic nature is presented.

• 出版日期2015-3-25