A simulation study of the effect of operating and design parameters on the performance of a water gas shift membrane reactor

作者：Boutikos Panagiotis; Nikolakis Vladimiros^*

来源：Journal of Membrane Science, 2010, 350(1-2): 378-386.

DOI：10.1016/j.memsci.2010.01.014

• Water gas shift
• Membrane reactor
• Reactor design

The goal of this work is to understand the effect of the relative values of membrane permselectivity, permeation flux and reaction rate on the performance of a water gas shift membrane reactor. This was achieved by simulating the operation of an isothermal tube-shell reactor. Its performance was evaluated based on the CO conversion and H(2) recovery, as well as the permeate and retentate H(2) molar fractions. The maximum enhancement of CO conversion has been observed when the Damkholer number (Da) is almost equal to the permeation number (Pe). Improvements in CO conversion can be achieved even when membranes with relatively low permselectivity values (similar to 10) are used. Further increase of permselectivity primarily increased the purity of the H(2) rich stream. The utilization of CO(2) selective instead of H(2) selective membranes could improve CO conversion only if the CO(2) content of the feed is higher than that of H(2). Finally, simulations using rate expressions that correspond to different detailed reaction mechanisms resulted only in slight differences in reactor performance.

• 出版日期2010-3-15