Ni(II) complex on a bispyridine-based porous organic polymer as a heterogeneous catalyst for ethylene oligomerization

作者:Kim Min Jeong; Ahn Sol; Yi Jigyoung; Hupp Joseph T; Notestein Justin M; Farha Omar K*; Lee Suk Joong*
来源:Catalysis Science & Technology, 2017, 7(19): 4351-4354.
DOI:10.1039/c7cy01274h

摘要

A Ni(II) catalyst incorporated into a new porous organic polymer, Ni(II)-POP-1, is prepared via a click reaction followed by metalation with NiCl2. It shows good catalytic activity for liquid-phase ethylene dimerization in the presence of Et2AlCl as a co-catalyst, generating 1-butene.