A N-tripodal Ligand Cu-Based Coordination Polymer with Good Catalytic Activity for the Reduction of 4-Nitrophenol

作者：Jin Kuang; Hu Jin-Song^*; Lv Chao-Nan; Liu Jun; Li Sheng-Yu; Cheng Ting-Ting; Zhou Chun-Hui; He Zhi-Wei; Zhang Ming-Dao

来源：Chinese Journal of Structural Chemistry, 2017, 36(8): 1361-1367.

DOI：10.14102/j.cnki.0254-5861.2011-1504

• coordination polymer
• catalysis
• reduction of nitrophenol

A complex {[Cu(tib)(2)(H2O)(2)]center dot(NO3)(2)}n (1) has been synthesized under N,N-dime-thylacetamide (DMA) and water conditions. The structure of complex 1 was characterized by single-crystal X-ray crystallography. It crystallizes in monoclinic, space group P2(1)/n with a = 10.6273(7), b = 11.4184(7), c = 13.4215(8) A, beta = 108.290(2), V = 1546.38(17) A(3), Z = 2, F(000) = 798, D-c = 1.667 g/cm(3) and mu = 0.786 mm(-1). Complex 1 exhibits a 3D network due to the existence of O-HO interaction between coordinated water and nitrate anions. Furthermore, complex 1 has a good catalytic activity for the reduction of 4-nitrophenol in NaBH4 solution.

• 出版日期2017-8-15
• 单位南京信息工程大学; 安徽理工大学