A missing link between chiral four- and five-coordinate complexes

作者：Lennartson Anders^*; Hakansson Mikael

来源：New Journal of Chemistry, 2015, 39(5): 3353-3356.

DOI：10.1039/c5nj00265f

We report total spontaneous resolution and absolute asymmetric synthesis of [Pd(hfacac)(2)P(o-tol)(3)] (hfacac = hexafluoroacetylacetonate, P(o-tol)(3) = tri(o-tolyl)phosphine), a chiral complex with a coordination geometry intermediate between square-planar, square pyramidal and trigonal bipyramidal.

• 出版日期2015