Mechanisms for the Trimethylaluminum Reaction in Aluminum Oxide Atomic Layer Deposition on Sulfur Passivated Germanium

作者：Delabie Annelies^*; Sioncke Sonja; Rip Jens; Van Elshocht Sven; Caymax Matty; Pourtois Geoffrey; Pierloot Kristine

来源：Journal of Physical Chemistry C, 2011, 115(35): 17523-17532.

DOI：10.1021/jp206070y

Germanium combined with high-kappa dielectrics is investigated for the next generations of CMOS devices. Therefore, we study reaction mechanisms for Al2O3 atomic layer deposition on sulfur passivated Ge using calculations based on density functional theory and total reflection X-ray fluorescence (TXRF). TXRF indicates 6 S/nm(2) and 4 Al/nm(2) after the first TMA/H2O reaction cycle, and growth inhibition from the second reaction cycle on. Calculations are performed on molecular clusters representing -GeSH surface sites. The calculations confirm that the TMA reaction does not affect the S content. On fully SH-terminated Ge, TMA favorably reacts with up to three -GeSH sites, resulting in a near tetrahedral Al coordination. Electron deficient structures with a Ge-S site shared between two Al atoms are proposed. The impact of the cluster size on the structures and reaction energetics is systematically investigated.

• 出版日期2011-9-8