mu-1,4-Bis(pyridin-4-ylmethyl)piperazine-kappa N-2:N %26apos;-bis[aquabis(3-bromo-5-carboxybenzoato-kappa O-1)copper(II)]

作者：Meyer Jodi L; LaDuca Robert L^*

来源：Acta Crystallographica Section E-Structure Reports Online, 2012, 68: M155-U721.

DOI：10.1107/S1600536812000979

In the title compound, [Cu-2(C8H4BrO4)(4)(C16H20N4)(H2O)(2)], slightly distorted square-planar-coordinated Cu-II ions are bound by one aqua ligand and two monodentate 3-bromo-5-carboxybenzoate anions, and linked into a centrosymmetric dinuclear molecule by a bridging 1,4-bis(pyridin-4-ylmethyl)piperazine (4-bpmp) ligand. In the crystal, molecules are connected into a supramolecular two-dimensional network parallel to (131) via O-H center dot center dot center dot O hydrogen bonds involving the aqua ligands and 3-bromo-5-carboxybenzoate carboxylate groups.

• 出版日期2012-2