Digital EPR with an arbitrary waveform generator and direct detection at the carrier frequency

作者：Tseitlin Mark; Quine Richard W; Rinard George A; Eaton Sandra S; Eaton Gareth R^*

来源：Journal of Magnetic Resonance, 2011, 213(1): 119-125.

DOI：10.1016/j.jmr.2011.09.024

• Arbitrary waveform generator
• High-speed digitizer
• Rapid scan EPR
• FID
• Electron spin echo

A digital EPR spectrometer was constructed by replacing the traditional bridge with an arbitrary waveform generator (AWG) to produce excitation patterns and a high-speed digitizer for direct detection of the spin system response at the carrier frequency. Digital down-conversion produced baseband signals in quadrature with very precise orthogonality. Real-time resonator tuning was performed by monitoring the Fourier transforms of signals reflected from the resonator during frequency sweeps generated by the AWG. The capabilities of the system were demonstrated by rapid magnetic field scans at 256 MHz carrier frequency, and FID and spin echo experiments at 1 and 10 GHz carrier frequencies. For the rapid scan experiments the leakage through a cross-loop resonator was compensated by adjusting the amplitude and phase of a sinusoid at the carrier frequency that was generated with another AWG channel.

• 出版日期2011-12