A heterogeneous, selective oxidation catalyst based on Mn triazacyclononane grafted under reaction conditions

作者:Schoenfeldt Nicholas J; Korinda Andrew W; Notestein Justin M*
来源:Chemical Communications, 2010, 46(10): 1640-1642.
DOI:10.1039/b920391e

摘要

A unique method has been developed to synthesize an active heterogeneous oxidation catalyst by the in situ grafting of a 1,4,7-trimethyl-1,4,7-triazacyclononane manganese complex on carboxylic acid-functionalized supports serving dual roles as surface tether and necessary co-catalyst, massively increasing total turnovers as compared to the homogeneous analog.