A 2D In(III) Coordination Polymer with Extended In-OH-In Chains

作者：Song, Yong-Juan; Han, Zheng-Bo^*; He, Yong-Ke; Zhang, Peng

来源：Journal of Chemical Crystallography, 2008, 38(12): 891-894.

DOI：10.1007/s10870-008-9401-3

• Synthesis
• Crystal structure
• Indium(III)
• Coordination polymer

A new indium(III) coordination polymer [In(OH)(Hpdc)(H2O)] (n) (1) H(3)pdc = 3,5-pyrazole-dicarboxylic acid) has been synthesized under hydrothermal condition and characterized by the elemental analysis and single crystal X-ray diffraction. X-ray diffraction analysis reveals that 1 (C5H5InN2O6) crystallizes in the monoclinic space group P2(1)/n, and features an interesting 2D layer constructed by 1D In-Hpdc chains and mu(2)-OH ligands. Unit cell parameters for 1: a = 10.406(2), b = 6.326(2), c = 11.631(2) angstrom, beta = 104.0(1)degrees, and Z = 4.

• 出版日期2008-12
• 单位辽宁大学