An iron (II) complex containing well-resolved 1D water chain and 1D chain of copper (II) complex with bis(tetrazoly)amine: Syntheses, crystal structures and properties

作者：Guan, Yang Fan; Zhou, Ai Ju; Wang, Dong Yao; Wang, Jing; Dong, Wen^*

来源：Journal of Molecular Structure, 2009, 938(1-3): 150-155.

DOI：10.1016/j.molstruc.2009.09.017

• H(2)bta
• Water cluster
• 1D chain
• Crystal structure

Two H(2)bta supramolecular complexes. [Fe(bpy)(2)(bta)] 6H(2)O (1) and [Cu(Hbta)(2)] 4H(2)O (2) (bpy = 2,2'-bipyridine, H(2)bta = bis(tetrazoly)amine). have been synthesized and characterized by single crystal X-ray diffraction analysis In mononuclear complex 1 a well-resolved water chain formed by hydrogen-bonding interactions has been observed, while 2 possesses a 1D spiral chain structure. The cyclic voltammogram (CV) of H(2)bta ligand and 1 have been investigated and the E(p) = -0.308 V for H(2)bta ligand and E(p) = -0.365 V for 1 may be attributed to the oxidation process of bta(-) - e -> bta and the negative value of E(p) show the H(2)bta can act as a good reducing ligand.

• 出版日期2009-12-16
• 单位广州大学