Analysis and interpretation of residence time distribution experimental curves in FM01-LC reactor using axial dispersion and plug dispersion exchange models with closed-closed boundary conditions

作者：Rivera Fernando F; Cruz Diaz Martin R^*; Rivero Eligio P; Gonzalez Ignacio

来源：Electrochimica Acta, 2010, 56(1): 361-371.

DOI：10.1016/j.electacta.2010.08.069

• FM01-LC
• RTD
• ADM
• PDE
• Closed-closed boundary

The liquid phase mixing flow pattern at low (20 <Re< 120) and intermediate liquid flow rate (120 < Re < 400) was studied by means of residence time distribution (RTD) experimental curve in an up-flow Filter Press electrochemical reactor (FM01-LC) bench scale. For this purpose, a plastic turbulence promoter was used with stainless-steel and platinised titanium structural meshes as electrodes in channel configuration. To visualize and determine the mixing flow pattern in the liquid phase, the stimulus-response technique was employed using dextran blue (D(M) 1.058 x 10(-11) m(2) s(-1), 25 degrees C, in water) as model tracer. A theoretical analysis and approximation RID experimental curves with axial dispersion model (ADM) and plug dispersion exchange model (PDE). with "closed-closed vessel" boundary conditions were used in order to establish a better approximation of the axial dispersion, stagnant zones, channelling and by-pass (preference flow) effects present at low and intermediate Re. RTD curves show that the liquid flow pattern in the FM01-LC deviates considerably from axial dispersion model at low Re, where the FM01-LC exhibits large channelling, stagnant zones, and dead zone. The POE model represents fairly this deviation from ideal flow (less dead zone).

• 出版日期2010-12-15