A new grid network based on diphosphopentamolybdate cluster supported transition metal complexes

作者：Lu Ying; Wang Enbo^*; Xu Xinxin; Ma Ying

来源：Journal of Coordination Chemistry, 2007, 60(1): 53-60.

DOI：10.1080/00958970600773887

• polyoxomolybdate
• crystal structure
• grid network
• supramolecular architecture
• supported copper complex

A new grid architecture built from diphosphopentamolybdate supported copper-imidazole, [{Cu-II(im)(4)}(2){H2Mo5P2O23}] . 3H(2)O . (im) (1) (im=imidazole), is reported. The structure of 1 features a 2-D grid network built by the interconnection of bisupporting diphosphopentamolybdate clusters, [{Cu-II(im)(4)}(2){H2Mo5P2O23}]; free water molecules and imidazole ligands fill the void of the crystal lattice. Crystal data for compound 1: Orthorhombic, space group Pnma, a=14.598(3) angstrom, b=21.059(4)angstrom, c=16.609(3) angstrom, alpha=beta=gamma=90 degrees; V=5106.1 angstrom(3); Z=4.

• 出版日期2007-1-10
• 单位东北师范大学