A Bioinspired Zn-II/Fe-III Heterobimetallic Catalyst for Thia-Michael Addition

作者:Lee Way Zen*; Wang Tzu Li; Chang Hao Ching; Chen Yi Ting; Kuo Ting Shen
来源:Organometallics, 2012, 31(11): 4106-4109.
DOI:10.1021/om300275a

摘要

A novel tetranuclear Zn-II/Fe-III heterobimetallic complex was synthesized, and the complex can efficiently catalyze the Michael addition of thiophenols to alpha,beta-unsaturated enones, even for tertiary carbon sulfur bond formation.

  • 出版日期2012-6-11