A non-fused mono-meso-free pentaphyrin and its rhodium(I) complex

作者:Yoneda Tomoki; Mori Hirotaka; Lee Byung Sun; Yoon Min Chul; Kim Dongho*; Osuka Atsuhiro
来源:Chemical Communications, 2012, 48(54): 6785-6787.
DOI:10.1039/c2cc32054a

摘要

5,10,15,20-Tetrakis(pentafluorophenyl) [22]pentaphyrin(1.1.1.1.1) 7 was synthesised and its bis-rhodium(I) complex 12 has been revealed to be a non-fused, yet planar pentaphyrin with an inverted pyrrole. Both 7 and 12 are aromatic, showing sharp Soret-like bands and diatropic ring currents.

  • 出版日期2012