Direct Energy Supply for Initiation of Some Photochemical Reactions in Macromolecules

作者:Ogul'Chansky Tymish Yu*; Vretik Lyudmila O; Yashchuk Valeriy M; Syromyatnikov Volodymir G; Kolendo Olexiy Yu
来源:Molecular Crystals and Liquid Crystals Science and Technology - Section A: Molecular Crystals and Liquid Crystals , 1998, 324: 223-230.
DOI:10.1080/10587259808047158

摘要

The possibility of using the direct electronic excitation energy transfer for energy supply to definite points of molecular systems for initiation of the chemical reactions or, on the contrary, for drainage of electronic excitation energy from the points of molecular systems suitable for reactions with the aim of their stabilization is examined. An analysis of Fries photorearrangement process in investigated compounds confirms the possibility of affecting the rate of Fries photorearrangement by means of electronic excitation energy supply.

  • 出版日期1998