摘要
New Pb-based 1212 compounds containing phosphorus have been discovered in the (Pb1-y P (y) )Sr-2(Y1-x Ca (x) )Cu2O (z) system; almost the single 1212 phase samples can be obtained for the composition range of 0.0a parts per thousand currency signxa parts per thousand currency sign0.6 and y=0.25. The crystal structure for each sample has a tetragonal symmetry with the typical lattice parameters a=0.3828 nm and c=1.182 nm. Among them, the sample with x=0.6 and y=0.25 shows the onset of resistivity drop at about 39 K and zero-resistivity at about 17 K. Moreover, the sample shows a diamagnetic signal at about 38 K. These phenomena are found to originate from superconductivity with the bulk feature.
- 出版日期2010-12