A novel iron complex for highly efficient catalytic hydrogen generation from the hydrolysis of organosilanes

作者：Teo Alan Kay Liang; Fan Wai Yip^*

来源：Chemical Communications, 2014, 50(54): 7191-7194.

DOI：10.1039/c4cc02852j

Hydrolytic oxidation of organosilanes based on an iron catalyst is described for the first time. The novel iron complex, [Fe(C6H5N2O)-(CO)(MeCN)(3)][PF6], exhibits excellent mediating power in the catalytic hydrolysis of organosilanes to produce dihydrogen and organosilanols with turnover numbers approaching 10(4) and turnover frequencies in excess of 10(2) min(-1) under ambient conditions.

• 出版日期2014