A novel colorimetric chemosensor for multiple target metal ions Fe2+, Co2+, and Cu2+ in a near-perfect aqueous solution: Experimental and theoretical studies

作者：Jung Jae Min; Lee Seong Youl; Kim Cheal

来源：Sensors and Actuators B: Chemical , 2017, 251: 291-301.

DOI：10.1016/j.snb.2017.05.055

• Cobalt(II) ion
• Iron(II) ion
• Copper(II) ion
• Colorimetric chemosensor
• Test kit
• Theoretical calculations

A selective and multifunctional chemosensor 1 for Fe2+, Co2+ and Cu2+ was designed and synthesized. 1 could simultaneously detect Fe2+, Co2+ and Cu2+ by changing its color from colorless to pink (Fe2+) and to yellow (Co2+ and Cu2+), respectively, in a near-perfect aqueous solution. The binding modes of 1 to Fe2+, Co2+ and Cu2+ were determined to be a 1:1, 2:1, and 1:1, respectively, through Job plot and ESI-mass spectrometry analysis. The detection limits (0.43 mu M, 0.11 mu M and 0.28 mu M) of 1 for Fe2+, Co2+ and Cu2+ were much lower than the US Environmental Protection Agency (EPA) guidelines (5.36 mu M for Fe2+ and 1.7 mu M for Co2+) and the WHO guideline (31.5 mu M for Cu2+) for the drinking water. Moreover, the chemosensor 1 could be used to quantify Fe2+, Co2+ and Cu2+ in water samples, and applied to test kits for detecting Fe2+, Co2+ and Cu2+. The sensing mechanisms of Co2+ and Cu2+ by 1 were supported by theoretical calculations.

• 出版日期2017-11