A 3D heteropolynuclear network with 4,6-connected (4(4)center dot 6(2))(4(8)center dot 6(6)center dot 8) topology: Synthesis, structure, thermal and magnetic properties

作者：Chen Pang Kuan; Che Yun Xia; Zheng Ji Min^*

来源：Inorganic Chemistry Communications, 2007, 10(2): 187-190.

DOI：10.1016/j.inoche.2006.10.015

• heteropolynuclear
• alternate layer
• 4,6-connected topology
• thermal property
• magnetic property
• hydrothermal synthesis

This paper describes a novel heteropolynuclear coordination polymer [Cd4Co2(m-BDC)(6)(HIm)(4)](n) (1) (m-H2BDC = 1,3-benzenedicarboxylic acid, Him = imidazole), which has been hydrothermally prepared and characterized by single-crystal X-ray diffraction, IR, ICP, XRPD, TGA, DSC, and element analysis. The overall architecture is constructed from alternate Co(II) and Cd layers arranged in ABAB mode, and affords a three-dimensional (3D) 4,6-conneccted (4(4) . 6(2))(4(8) . 6(6) - 8) topological network. Furthermore, magnetic property of 1 has also been studied in the temperature range of 5-300 K.

• 出版日期2007-2
• 单位南开大学