A Tetranuclear, Macrocyclic 3d-4f Complex Showing Single-Molecule Magnet Behavior

作者:Feltham Humphrey L C; Clerac Rodolphe; Powell Annie K; Brooker Sally*
来源:Inorganic Chemistry, 2011, 50(10): 4232-4234.
DOI:10.1021/ic2003639

摘要

[Cu(3)(II)Tb(III)(L(Pr))(NO(3))(2)(MeOH)(H(2)O)(2)]-(NO(3))center dot 3H(2)O is a rare example of a 3d-4f single-molecule magnet prepared using a macrocyclic ligand: at low T, it exhibits frequency-dependent alternating-current susceptibility, indicative of slow relaxation of the magnetization.

  • 出版日期2011-5-16