A Coordination Chemistry Approach for Lithium-Ion Batteries: The Coexistence of Metal and Ligand Redox Activities in a One Dimensional Metal Organic Material

作者：Li, Gaihua; Yang, Hao; Li, Fengcai; Cheng, Fangyi; Shi, Wei^*; Chen, Jun; Cheng, Peng^*

来源：Inorganic Chemistry, 2016, 55(10): 4935-4940.

DOI：10.1021/acs.inorgchem.6b00450

• CATHODE MATERIALS
• HIGH-PERFORMANCE
• ENERGY-STORAGE
• FRAMEWORKS
• ANODES
• DICARBOXYLATE
• COMPLEXES
• POLYMERS
• LI

We demonstrate herein the use of a one-dimensional metal-organic material as 4 new type of electrode material for lithium. ion batteries.(LIBs) in place of the classic porus three-dimensional materials, which are subject to the size of the channel for lithium ion diffusion and blocking of the windows of the framework by organic solvents during the charging and discharging processes. Introducing a one-dimensional coordination compound can keep organic active substances in soluble in the electrolyte during the charging and discharging processes, providing a facile and general new system for further studies. The results show that both the aromatic ligand and the : metal center can participate in lithium storage simultaneously, illustrating,: a new. energy storage mechanism, that has been well characterized by X-ray photoelectron spectroscopy, electron paramagnetic resonance spectroscopy, and cyclic voltammetry. In addition, the fact that the one-dimensional chains are linked by weak hydrogen bonds rather than strong pi-pi stacking interactions or covalent bonds is beneficial for the release of capacity entirely without the negative effect of burying the active sites.

• 出版日期2016-5-16
• 单位南开大学