Application of nitrogen-doped graphene nanosheets in electrically conductive adhesives

作者：Pu Nen Wen; Peng You Yu; Wang Po Chiang; Chen Chun Yu; Shi Jia Nan; Liu Yih Ming; Ger Ming Der^*; Chang Chien Liang

来源：Carbon, 2014, 67: 449-456.

DOI：10.1016/j.carbon.2013.10.017

Nitrogen-doped graphene nanosheets (N-GNSs) were used as a conductive filler for a polymer resin adhesive and as a performance improver for a silver-filled electrically conductive adhesive (ECA). The N-GNS samples were prepared by the chemical-intercalation/thermal-exfoliation of graphite followed by a thermal treatment in NH3. Only 1 wt.% of N-GNSs was required for the adhesive to reach a percolation threshold, and the performance using N-GNSs was much better than that obtained using carbon black or multi-walled carbon nanotubes (MWCNTs). The effect of N-GNS or MWCNT additives on reducing the electrical resistivity of Ag-particle filled ECAs at low Ag loading ratios was also investigated. With 30 wt.% of Ag filler, the polymer resin was still non-conducting, while a resistivity of 4.4 x 10(-2) SI-cm was obtained using an Ag/N-GNS hybrid filler fortified with only 1 wt.% of N-GNSs due to large specific surface area, high aspect ratio, and good electrical conductivity of the doped graphene.

• 出版日期2014-2
• 单位中国人民解放军国防大学