A reddish La2O2S-based long-afterglow phosphor with effective absorption in the visible light region

作者：Liu, Guodong; Zhang, Qinghong; Wang, Hongzhi^*; Li, Yaogang

来源：Materials Science and Engineering B-Solid State Materials for Advanced Technology, 2012, 177(3): 316-320.

DOI：10.1016/j.mseb.2011.12.045

• La2O2S phosphors
• UV-vis absorption
• Luminescent properties
• Long afterglow

Sm3+-activated La2O2S phosphors with good crystallinity were prepared by solid-state reaction. The formation mechanism of La2O2S formation was assumed and the phase change with different temperatures was discussed. The luminescence properties of phosphors with different sintering temperatures and different doping concentrations of Sm3+ were investigated. The emission peak at 605 nm showed a well intensity can be attributed to the (4)G(5/2) -> H-6(7/2) transition of Sm3+. The optical absorption of La2O2S phosphors showed a stronger intensity in UV-vis region comparing with the Y2O2S phosphors. The long afterglow properties were investigated after the phosphors were excited with a fluorescent lamp. Phosphorescence lasted for about 3 min in the limit of light perception of the dark-adapted human eye (0.32 mcdm(-2)).

• 出版日期2012-2-25
• 单位东华大学