A highly adaptable catalyst/substrate system for the synthesis of substituted chromenes

作者:Aponick Aaron*; Biannic Berenger; Jong Michael R
来源:Chemical communications, 2010, 46(36): 6849-6851.
DOI:10.1039/c0cc01961e

摘要

The gold(I)-catalyzed endo-cyclization of o-(1-hydroxyallyl)phenols to form chromenes is reported. The title compounds are prepared in high yield from readily available substrates. The system tolerates both electron rich and deficient aryl rings and a high degree of substitution on the allyl moiety.

  • 出版日期2010